Functionalised [(NHC)Pd(allyl)Cl] Complexes: Synthesis, Immobilisation and Application in Cross-Coupling and Dehalogenation Reactions

نویسندگان

  • John-Michael Collinson
  • James D. E. T. Wilton-Ely
  • Silvia Díez-González
چکیده

A novel NHC–palladium(II) (NHC = N-heterocyclic carbene) complex and its immobilised version have been prepared and fully characterised. Optimisation studies led to good catalytic activities in Suzuki-Miyaura cross coupling and chloroarene dehalogenation reactions. Furthermore, the unexpected palladium-mediated transfer hydrogenation of a carbonyl compound is reported.

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تاریخ انتشار 2016